Bis(1-ferrocenylethanone oximato)triphenylantimony(V)
نویسنده
چکیده
In the title compound, [Fe(2)Sb(C(5)H(5))(2)(C(6)H(5))(3)(C(7)H(7)NO)(2)] or [Sb(C(6)H(5))(3){Fe(C(5)H(5))(C(7)H(7)NO)}(2)], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The crystal structure is stabilized by two inter-molecular C-H⋯π inter-actions.
منابع مشابه
Bis(2-hydroxybenzaldehyde oximato-κO)triphenylantimony(V)
The mol-ecule of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 2-hydroxy-benzaldehyde oximate ligands. An intra-molecular O-H⋯N inter-action is...
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